PE
Polyethylene
Polyethylene is one of the most frequently produced synthetic
materials. During the course of the day you will meet a lot of things,
consisting of PE. The field of application reachs from small plastic
pags, pails over crates of beer, to pipes or dustbins.
Polyethylene can be divided in multiple variations:
•
PE-HD or HDPE, soft-PE
•
PE-LD or LDPE, hard-PE
"HD" denotes polyethylene with High Density. These high density is caused by low
arborescent polymer chains. "LD" denotes PE with "low density". These polymers
exhibit strong arborescent polymer chains, resulting in a lower density. The varied
grad of arborescent is generated by different process parameter during the
fabrication.
Manufacturing
The production of polyethylene occurs by polymerisation of the gas ethene.
PE-HD will be produced by the Ziegler-Natta or the Philips method. During the
Philips procedure temperatures between 80 and 180 °C and pressures between 30
and 40 bar will be applied. Furthermore catalysts like chromium oxide come into
operation. The Ziegler-Natta method uses titanester, aluminiumalkyl and
titanhalogenid as catalysts and works at pressures between 5 and 50 bar and
temperatures in the range of 20 to 150 °C.
The manufacturing of PE-LD occurs at temperatures between 100 and 300 °C and
pressures in the range of 1500 to 3000 bar. Additional, peroxids or oxigin come into
operation as initiators.
Properties
Overview
name
polyethylene
classification
- polymer
- thermoplastic
Manufacturing
monomers
- ethene C2H4
Properties
aggregate state
solid
general
- transparent to dimmish
- high flammability
- permeable for carbon dioxided, oxigen
and flavouring substances
- high chemical resistance
- waxy
PE-HD
PE-LD
Mechanical
density
0,97 g/cm3
0,92 g/cm3
hardness
tensile strength
~ 23 MPa
breaking elongation
friction coefficient
0,3
Electrical
dielectric constant
2,5 (103 - 106 Hz)
2,3 (103 - 106 Hz)
specific resistance
> 1010 Ω * mm
dielectric strength
30 kV/mm
Thermal
melting temperature
129 °C
110 °C
heat capacity
1,86 J/(g*K)
heat conductivity
combustion heat
5 MJ/kg
operation temperature
-60 to +70 °C
-60 to +70 °C
Optical
refractive index
Application
•
PE is tasteless and inodorus, products made of polyethylene contain no
plasticiser in general
•
→ Thus, this polymer is applicaple for sensible sections (medical secstion)
•
PE-HD is mainly used in form of hollowware
•
→ Thus small bottles for soft drinks or even huge hoppers with a capacity over
1000 l are made of high density PE
•
Foils consisting of PE-HD exist too
•
but for foils, PE-LD is mainly used for the fabrication
•
→ Thus, shrink films, bags or litterbags consist of PE-LD
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