ETFE
Ethylene-Tetrafluoroethylene
ETFE is a copolymer, made of the monomers ethylene
(ethene) and tetrafluorethylene (tetrafluorethene). Thus,
ETFE amongs to the fluoropolymers
Manufacturing
The production of ETFE can be devided in 3 parts:
1.
polymerisation
2.
granulation
3.
extrusion/ sintering
The copolymer ETFE consits of about 75% tetrafluoroethylene and 25% ethylene.
•
Calcium fluoroide CaF2 will be blend with chloroform CHCl3 and hydrogen
sulfate [HSO4]- → chlorodifluoromethane CHClF2
•
chlorodifluoromethane by pyrolysis → tetrafluoroethylene (C2F4)
•
tetrafluoroethylene + ethene → ETFE ([C4F8H8]n)
Properties
Overview
name
ethylene-tetrafluoroethylene
classification
- copolymer
- thermoplastic
Manufacturing
monomers
- tetrafluoroethene C2F4
- ethene C2H4
production
- pyrolysis of chloroform
- polymerisation
Properties
aggregate state
solid
general
- good puncture resistance
- good tensile strength at break
- excellent weather stability
- excellent UV-consistence
- high chemical resistance
- wide temperature range of applicability
- hardly inflammable
Mechanical
density
1,7 g/cm3
hardness
D-70
tensile strength
~ 40 MPa
breaking elongation
300 %
friction coefficient
0,4
Electrical
dielectric constant
2,6 (103 - 106 Hz)
specific resistance
> 107 Ω * mm
dielectric strength
65-90 kV/mm
Thermal
melting temperature
270 °C
heat capacity
heat conductivity
combustion heat
12 MJ/kg
operation temperature
max. 160 °C
Optical
refractive index
Application
•
in form of foils and membrane pillows for building industry
•
→ greenhouses, sport stadiums (Allianz- Arena in Munich), notatoriums, and
more...
•
separating foil for composite materials
•
protection layer for solar cells
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